Product ID:TORDON K HERBICIDE,87096,22 K
MSDS Date:03/29/1989
FSC:6840
NIIN:01-432-6855
MSDS Number: CCJJP

DOW CHEMICAL U.S.A.

CHEMICAL AND METALS DEPARTMENT
MIDLAND, MI 48674
US

Emergency Phone: 517-636-4400

Info Phone: 800-258-2436

Cage: 96717

GOURMET INQUE LTD

ELK GROVE VILLAGE, IL 60007-1555 US

Telephone: 800-542-1042

Cage: 0TNN7

4-AMINO-3,5,6-TRICHLOROPICOLINIC ACID, (PICLORAM) POTASSIUM

CAS: 2545-60-0

RTECS: TJ7526000

Fraction By Weight: 24.4%

INERT MATERIALS; TOTAL PERCENTAGE OF INGREDIENTS 2, 3 AND 4

Fraction By Weight: SEE ING

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: SEE # 2%

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

DISPERSING AGENT

Fraction By Weight: SEE # 2%

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN.
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. ACUTE- MAY CAUSE SEVERE EYE IRRITATION.
PROLONGED/REPEATED SKIN CONTACT MAY CAUSE IRRITATION, EVEN A BURN.
MAY BE ABSORBED THROUGH SKIN. SINGLE EXPOSU RE TO VAPORS IS NOT
LIKELY TO BE HAZARDOUS. INGESTION OF LARGE AMOUNTS MAY CAUSE
INJURY. CHRONIC- MAY CAUSE LIVER EFFECT
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SEVERE IRRITATION, BURN, PAIN, TEARING

First Aid:CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH
WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN.
SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF NEEDED. ORAL:IF LARGE AMOUNTS ARE INGESTED, INDUCE
VOMITING. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER
GIVE FLUID OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS
CONVULSIONS.

Flash Point Method:TCC
Flash Point:214F,101C
Autoignition Temp:Autoignition Temp Text:1022F
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO2), ALCOHOL FOAM
OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE
MODE. AVOID WATER FROM FIRE FIGHTING INTO STREAMS.
Unusual Fire/Explosion Hazard:CORROSIVE AND TOXIC GASES MAY BE FORMED.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA.
ABSORB SPILLS WITH AN ABSORBENT MATERIAL SUCH AS
BENTONITE/CLAY/SAND. COLLECT ABSORBENT AND PLACE IN PLASTIC-LINED
METAL DRUM FOR DISPOSAL. SCRUB SPILL AREA WITH A STRONG DETERGENT
AND RINSE WITH WATER.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
MATERIALS. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM FOOD AND
FEED.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING
VAPORS/MISTS. WASH THOROUGHLY AFTER HANDLING MATERIAL AND BEFORE
EATING OR DRINKING. DO NOT INGEST.

Respiratory Protection:NONE NORMALLY REQUIRED. WHEN RESPIRATORY
PROTECTION IS REQUIRED, USE A NIOSH APPROVED AIR-SUPPLIED
RESPIRATOR.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Protective Gloves:RUBBER/LATEX FOR PROLONG/REPEAT CONTACT
Eye Protection:CHEMICAL GOGGLES RECOMMENDED
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:DO NOT PERMIT EATING, DRINKING OR SMOKING NEAR
THIS MATERIAL.
Supplemental Safety and Health
EPA REGISTRATION NUMBER: 464-421.

HCC:T5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:23 @ 68F
Spec Gravity:1.160
Solubility in Water:INFINITE
Appearance and Odor:BROWN LIQUID

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, STRONG ACIDS
Stability Condition to Avoid:IGNITION SOURCES IF TEMPERATURE IS NEAR OR
ABOVE FLASH POINT (214F)
Hazardous Decomposition Products:HYDROGEN CHLORIDE, NITROGEN OXIDES

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. BURY IN NON-CROP LAND AWAY FROM WATER SUPPLIES
OR DISPOSE OF IN A LANDFILL APPROVED FOR PESTICIDES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.